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CH3041
ALKALINITY III
• The major basic ions present in natural
  waters are HCO3-, CO32-, OH- .
Concentration dependence
• acidic pH         H2CO3 = “CO2”
• slightly acidic H2CO3, HCO3-
• slightly basic  HCO3-, CO32-
•  basic pH         CO32-, OH- 
•The alkalinity serves as a
reservoir for inorganic carbon and thus as an indicator of the ability of the water to support biota – it is also a buffer system.
• As Dissolved Inorganic Carbon (pH7 HCO3-)
is used up a  water will become more basic.
• Eventually the water becomes too basic &
  algal biomass production stops.
Species Distribution Diagram