• PolyChlorinated Biphenyls are
derived from the parent
cmpd
Biphenyl by
chlorination (EAS).
• PCBs were used as dielectric coolant fluids in transformers & capacitors.
• Excellent
electrical & thermal insulation,
low flammability &
slight vapour pressure, chemically inert. High
KOW
low H2O solubility
• The chlorination
proceeds at each of the
positions resulting in
mixtures of the 209
congeners (member
of a family of related cmpds,
the family is based on
structure/functional grps).