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CH3041
PCBs I
• PolyChlorinated Biphenyls are
derived from the parent cmpd
Biphenyl by chlorination (EAS).
• PCBs were used as dielectric coolant fluids in transformers & capacitors.
• Excellent electrical & thermal insulation,
low flammability & slight vapour pressure, chemically inert.    High KOW  low H2O solubility
• The chlorination proceeds at each of the
positions resulting in mixtures of the 209
congeners (member of a family of related cmpds,
the family is based on structure/functional grps).