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CH3041
MEASUREMENT OF CEC
1) 3 x 1.0M NH4Cl
• analyse metals
gives Ca2+, Mg2+..
• 2) 1.0M NaCl
• analyse NH4+
gives the total CEC
The CEC is the cmol/kg
of NH4+   ie. millimol / 100g
• Smectite 120 cmol / kg
• Other soil materials with
  large CEC’s are:
 Allophane CEC 60   
   (in 3-5nm spheres)
 Organic matter  CEC 350 
   (carboxyl groups)