(b) Reaction with oxygen
Group 1A +
O2
Ø lithium ® Li2O (oxide; O2-)
Ø sodium ® Na2O2 (peroxide; O22-)
Ø K, Rb, Cs ® MO2 (superoxide;
O2-)
• the differences are due to the different sizes of the anions and cations and the most stable ionic lattice that results.
eg. small cation + small anion ®
stable solid
• Airpacks (firefighters) use O2 stored in KO2.