Transition metals owe their location in the periodic table to the filling of the d
subshells. When these metals are oxidized, however, they lose their outer s electrons
before they lose electrons from the d subshell. For example, the electron
configuration of Fe is [Ar]4s23d6,
whereas that of Fe2+ is [Ar]3d6.
Formation of Fe3+ requires loss of one 3d electron,
giving [Ar]3d5. Most transition-metal ions contain partially occupied
d subshells.