Numerical prefixes.
• The occurrence of two or more
ligands (or metal atoms) is indicated by the prefixes di, tri, tetra, penta or hexa
• For polysyllabic organic bi-/multi- dentate
ligands and/or ligands containing di, tri etc then bis (2) and tris(3) are used to reduce
confusion with the naming inside the ligand (which will be di,
tri ...).
eg.
[Ni(en)2]Cl2 (en = NH2CH2CH2NH2) bis(ethylenediamine)nickel(II)
chloride