CH1012
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3
1 COMPONENT SYSTEMS II
Vapour Pressure
increases
with T.
T
F
= freezing point
T
B
= boiling point
(V.P. = external pressure)
Cairns
(0m,760 torr)
= 100
o
C
Bartle Frere
(1615m,613 torr)
= 94
o
C
liquid
phase boundary
gas
intermolecular
forces alter
b.p.
Fraction of molecules with
sufficient E
k
to escape liquid