• For d block T-Metals we can have electronic
transitions within the d orbitals.
• These transitions are lower in energy and correspond to
energy in the visible
region.
• The complexes are therefore coloured due to their absorption of some of the incident light.
• The variety of different colours found in TM complexes are
explained by the way in which ligands influence the energies of the
d-orbitals ("Crystal Field Theory").